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The Journal of Chemical Physics | Vol.18, Issue.8 | | Pages 1081

The Journal of Chemical Physics

Substituted Methanes. IV. Vibrational Spectra and Calculated Thermodynamic Properties of Deuterotrichloromethane

John R. Madigan Forrest F. Cleveland William M. Boyer Richard B. Bernstein  
Abstract

Abstract Raman displacements, semiquantitative relative intensities, quantitative depolarization factors, and wave numbers and percent transmission for the infra‐red bands in the region 400–5000 cm−1 have been obtained for CCl3D. Thermodynamic properties—heat content, free energy,entropy, and heat capacity—have been calculated from the spectroscopic and molecular structure data, to a rigid rotator, harmonic oscillator approximation, for nine temperatures from 298.16° to 1000°K.

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Substituted Methanes. IV. Vibrational Spectra and Calculated Thermodynamic Properties of Deuterotrichloromethane

Abstract Raman displacements, semiquantitative relative intensities, quantitative depolarization factors, and wave numbers and percent transmission for the infra‐red bands in the region 400–5000 cm−1 have been obtained for CCl3D. Thermodynamic properties—heat content, free energy,entropy, and heat capacity—have been calculated from the spectroscopic and molecular structure data, to a rigid rotator, harmonic oscillator approximation, for nine temperatures from 298.16° to 1000°K.

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John R. Madigan Forrest F. Cleveland William M. Boyer Richard B. Bernstein,.Substituted Methanes. IV. Vibrational Spectra and Calculated Thermodynamic Properties of Deuterotrichloromethane. 18 (8),1081.

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