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Chemical & Engineering News Archive | Vol.35, Issue.38 | | Pages 90–94

Chemical & Engineering News Archive

New Vinyl Epoxy Plasticizers Cyclohexene oxide compounds offer promise as light-heat stabilizers in poly-(vinyl chloride) resins

Abstract

132 ACS NATIONAL MEETING Paint, Plastics,& Printing Ink Chemistry Within a year some new PVC plasticizers - stabilizers stabilizers could be in limited production, and will make a lot of news. Key factor—the cyclohexene oxide group. The compounds, for which peracetic acid is the epoxidizing agent, may answer the crying need for a greater variety of epoxy plasticizers and stabilizers. To date only two epoxy classes have commercial status: epoxy fatty acid esters and the glycidyl ethers. FMC's Frank P. Greenspan estimated to the Division of Paint, Plastics, and Printing Ink Chemistry that some 30 million pounds of the epoxy fatty acid esters will be produced in 1957—75% epoxy triglycerides and 25% alkyl epoxystearates. He and Becco Division's R. J. Gall point to dialkyl 4,5-epoxycylohexane-l ,2-dicarboxylates (also referred to as epoxy-hexadrophthalate esters) as materials which combine the stabilizing properties of epoxy fatty acid esters with good plasticizing properties characteristic of phthalates. ...

Original Text (This is the original text for your reference.)

New Vinyl Epoxy Plasticizers Cyclohexene oxide compounds offer promise as light-heat stabilizers in poly-(vinyl chloride) resins

132 ACS NATIONAL MEETING Paint, Plastics,& Printing Ink Chemistry Within a year some new PVC plasticizers - stabilizers stabilizers could be in limited production, and will make a lot of news. Key factor—the cyclohexene oxide group. The compounds, for which peracetic acid is the epoxidizing agent, may answer the crying need for a greater variety of epoxy plasticizers and stabilizers. To date only two epoxy classes have commercial status: epoxy fatty acid esters and the glycidyl ethers. FMC's Frank P. Greenspan estimated to the Division of Paint, Plastics, and Printing Ink Chemistry that some 30 million pounds of the epoxy fatty acid esters will be produced in 1957—75% epoxy triglycerides and 25% alkyl epoxystearates. He and Becco Division's R. J. Gall point to dialkyl 4,5-epoxycylohexane-l ,2-dicarboxylates (also referred to as epoxy-hexadrophthalate esters) as materials which combine the stabilizing properties of epoxy fatty acid esters with good plasticizing properties characteristic of phthalates. ...

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.New Vinyl Epoxy Plasticizers Cyclohexene oxide compounds offer promise as light-heat stabilizers in poly-(vinyl chloride) resins. 35 (38),90–94.

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