Graphene oxide based molecularly imprinted polymers modified with β‐cyclodextrin were prepared as solid‐phase extraction column sorbents for specific recognition and sensitive detection of di(2‐ethylhexyl) phthalate in water samples. The morphology and composition of synthesized sorbents were characterized by scanning electron microscopy, thermo‐gravimetric analysis, Raman spectroscopy, and Fourier‐transform infrared spectroscopy. The conditions affecting the performance of extraction procedures such as desorption solvent types and volume, sample pH and volume were investigated. The loading capacity (8.2 μg/mg) of the prepared sorbents increased eight times after modification with β‐cyclodextrin. The developed extraction procedures coupled to high‐performance liquid chromatography exhibited good linearity (0.2–500 μg/L), low limit of detection (0.052 μg/L), and good precision (relative standard deviation˂5.7%) under optimized conditions. The developed solid‐phase extraction technique with prepared sorbents has been successfully applied in extracting trace di(2‐ethylhexyl) phthalate from real natural waters with high efficiency, good selectivity, and desirable recoveries.

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fouriertransform infrared specific recognition and sensitive detection of di2ethylhexyl phthalate linearity oxide highperformance liquid chromatography extracting trace di2ethylhexyl phthalate precision real natural waters solidphase extraction column sorbents raman spectroscopy selectivity molecularly imprinted polymers capacity limit scanning electron microscopy thermogravimetric desirable recoveries detection

Chengjun Wang, Lidong Cheng, Lin Zhang, Yuegang Zuo,.Graphene oxide based molecularly imprinted polymers modified with β‐cyclodextrin for selective extraction of di(2‐ethylhexyl) phthalate in environmental waters. 42 (42),.

Chengjun Wang, Lidong Cheng, Lin Zhang, Yuegang Zuo,"Graphene oxide based molecularly imprinted polymers modified with β‐cyclodextrin for selective extraction of di(2‐ethylhexyl) phthalate in environmental waters" 42

Chengjun Wang, Lidong Cheng, Lin Zhang, Yuegang Zuo,"Graphene oxide based molecularly imprinted polymers modified with β‐cyclodextrin for selective extraction of di(2‐ethylhexyl) phthalate in environmental waters"